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Potassium chloride

Properties, data and information sources.

 

Contents

Potassium chloride is an inorganic compound from the group of halides, chemically described as the potassium salt of Hydrochloric Acid. In this substance, potassium exists as positively charged K+ cations and chlorine as negatively charged chloride anions Cl-.

 

Names and Identifiers

Name
Potassium chloride
Formula
ClK
KCl
Molar mass
74.548 (g/mol)
CAS registry number
7447-40-7
EC number EINECS
231-211-8
InChI Key
WCUXLLCKKVVCTQ-UHFFFAOYSA-M

Other names, synonyms
Muriate of potash; Sylvite; Potassium salt; Sylvine

INCI name
Potassium chloride

 

Chemical formulas

Molecular formula and structural formula of Potassium chloride:

 

ClK or KCl

Mr = 74.5483 g/mol
SMILES: [Cl-].[K+]

 

Data and Properties

Pure potassium chloride is usually a white, odorless, strongly salty and slightly bitter tasting, hygroscopic powder or colorless, elongated, prismatic or cubic crystals.

solubility:
+ Readily soluble in water (see table below), glycerol.
- Unsoluble in ethanol (0,00288 g/L at 25 °C), acetone, diethyl ether.
melting point
770 °C
boiling point
1420 °C
density
1.984 g cm-3 at 20 °C

pKa value
pK1a = -7
refractive index
nD = 1.4902
standard enthalpy of formation
-436 kJ/mol at 25 °C
standard entropie
83 J/(mol K) at 25 °C
magnetic susceptibility χ
-39.0 × 10-6 cm3 mol-1
crystal structure:
Face-centered cubic, space group Fm3m - No. 225; a = 629.2 pm. Octahedral coordination of the ions.

 

Potassium Chloride Solution

Solid potassium chloride is readily soluble in water, depending on the temperature:

TemperatureSolubility [g/L]
0 °C281
10 °C312
20 °C339.7
25 °C355
30 °C372
40 °C402
50 °C431

 

A completely saturated potassium chloride solution is obtained at 20 °C by dissolving 339.7 grams of KCl in one liter of water. The boiling point of this solution is 108.6 °C, and its density is 1.18 g/cm3.

The following table shows some data and properties (molar concentration c, mass concentration β, density ρ, refractive index nD) of aqueous potassium chloride solutions as a function of the mass fraction of KCl. The values ​​are valid for a temperature of 20 °C.

 

Mass
percent
c
[mol/L]
β
[g/L]
Molality b
[mol/kg]
Density ρ
[g cm-3]
Refractive Index
nD
0.5 %0.0674.9950.0671.00141.3337
1 %0.13510.0640.1351.00461.3343
2 %0.27120.2030.2741.01101.3357
3 %0.40930.4900.4151.01741.3371
4 %0.54940.9270.5591.02391.3384
5 %0.69151.5130.7061.03041.3398
6 %0.83562.2480.8561.03691.3411
7 %0.98073.0571.0101.04341.3425
8 %1.12784.0161.1661.05001.3438
9 %1.27695.1241.3271.05661.3452
10 %1.426106.3061.4901.06331.3466
11 %1.579117.7121.6581.07001.3479
12 %1.733129.1921.8291.07681.3493
13 %1.890140.8962.0041.08361.3507
14 %2.048152.6752.1841.09051.3521
15 %2.208164.6032.3671.09741.3535
16 %2.370176.6792.5551.10431.3549
17 %2.534188.9052.7471.11141.3563
18 %2.701201.3552.9451.11851.3577
19 %2.869213.8793.1471.12561.3592
20 %3.039226.5523.3541.13281.3606
21 %3.211239.3753.5661.13991.3622
22 %3.386252.4213.7831.14741.3635
23 %3.562265.5414.0071.15451.3651
24 %3.742278.9604.2361.16231.3665
25 %3.924292.5284.4711.17011.3679

 

Electrolyte solutions containing potassium chloride, such as Ringer´s solution, are used in medicine and contain 4 to 5 mmol/L potassium ions.

A 3 molar or 3M KCl solution (c = 3 mol/l) serves as a storage solution for many types of pH electrodes and ORP probes; the solution is obtained from 223.644 g of potassium chloride in a volumetric flask and making up the volume to one liter with distilled water.

The relative humidity above a saturated KCl solution in a container is a constant 85% at 23°C.

 

Conductivity

Potassium chloride solutions conduct electricity depending on temperature and concentration. They are used - along with other salt solutions - for calibrating conductivity meters. The electrical conductivity (conductance values ​​κ in millisiemens per cm) of various KCl solutions are shown in the following tables.

The first table lists the conductivity of a potassium chloride solution as a function of the mass percent of KCl in the aqueous solution; all values ​​apply to a temperature of 20 °C:

Mass-% KClg/Lkappa κ [mS/cm]
0.54.9958.2
110.06415.7
220.20329.5
551.51371.9
10106.306143
15164.604208

 

The second table lists typical values ​​for preparing a calibration solution (in grams of KCl per liter of pure distilled water). The data refers to a temperature of 25 °C.

g/Lmol/Lκ in mS/cm
000.02
0.04170.000560.084
0.07450.0010.700
0.74540.011.413
1.49090.022.765
2.98190.045.446
7.45480.1012.880
37.27410.5056.6
74.54831.00111.8
110.09662.00212.0

 

Percentage and isotopic composition:

Mass-related elemental composition and isotope proportions of the compound Potassium chloride - ClK - calculated based on molecular mass.

Symbol
Element E
Number x
of atoms Ex
Data of the element
and isotopes *
Percentages
of isotopes
Percentage of
Ex in formula mass
Cl
Chlorine
1ΣAr = 35.45 u
35Cl: 34.96885 u [75,80 %]
36Cl: 35.96831 u [<< 1 %]
37Cl: 36.9659 u [24,2 %]
 
35Cl: 36.04522 %
36Cl: trace
37Cl: 11.50784 %
47.5531 %K
Potassium
1ΣAr = 39.0983 u
39K: 38.96371 u [93,2581 %]
40K: 39.964 u [0,0117 %]
41K: 40.96183 u [6,7302 %]
 
39K: 48.91102 %
40K: 0.00614 %
41K: 3.52978 %
52.4469 %

*) The third column lists the atomic masses or isotope masses of the elements involved and - in square brackets - the natural isotope composition.

 

More calculated data

The molar mass is M = 74.5483 grams per mole.

The amount of substance in one kilogram of the substance is n = 13.414 mol.

The amount of substance in one gram of the substance is n = 0.013 mol.

Monoisotopic mass: 73.932559185 Da - related to 35Cl39K.

 

Potassium chloride as Active Ingredient

ATC Code:
A12BA01
A12BA51
B05XA01

Potassium chloride is used medically to treat hypokalemia (low blood potassium) as a source of the mineral potassium. The substance is also a component of various electrolyte solutions, such as Ringer´s solution, and an additive in peritoneal dialysis solutions. An overdose can lead to hyperkalemia, which can significantly disrupt cell signaling.

For detailed information on the active ingredient, see: DrugBank DB00761.

 

Use in food

E-Nummer: E508

Potassium chloride is an approved food additive in the EU, used as a flavor enhancer. It is primarily used in ready-made meals, spice mixes, low-sodium or reduced-calorie foods, and table salt. There is no maximum limit on the amount permitted (quantum satis).

EU: Status and regulations see EU Food Additives DB Ref. Number 3206.

 

Use in Cosmetics

INCI Name: Potassium chloride

Ingredient in cosmetics and personal care products used to regulate the viscosity of the preparation.

Source: CosIng (Cosmetic Ingredient Database) number: 36948.

 

External Sources

PubChem:ID 4873ChemSpider:ID 4707Kegg database DBGET:ID D02060UNII of the FDA (USA):Unique Ingredient Identifier 660YQ98I10EPA CompTox Chemicals Dashboard:DTXSID5021178

 

Manufacturers and Sources of Supply

The table below lists producers and suppliers of Potassium chloride as a commercial chemical for laboratories, research, industry and production with the corresponding contact details.

 

Literature Sources

[0] - Specialist and research articles in scientific journals via PubMed: Potassium_chloride.

[1] - Maged Younes, Gabriele Aquilina, Laurence Castle et al.:
Re‐evaluation of hydrochloric acid (E 507), potassium chloride (E 508), calcium chloride (E 509) and magnesium chloride (E 511) as food additives.
In: EFSA Journal, (2019), DOI 10.2903/j.efsa.2019.5751.

 


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Last update: 2026-01-07


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