Potassium chloride is an inorganic compound from the group of halides, chemically described as the potassium salt of Hydrochloric Acid. In this substance, potassium exists as positively charged K+ cations and chlorine as negatively charged chloride anions Cl-.
Other names, synonyms
Muriate of potash; Sylvite; Potassium salt; Sylvine
INCI name
Potassium chloride
Molecular formula and structural formula of Potassium chloride:
ClK or KCl
Mr = 74.5483 g/mol
SMILES: [Cl-].[K+]
Pure potassium chloride is usually a white, odorless, strongly salty and slightly bitter tasting, hygroscopic powder or colorless, elongated, prismatic or cubic crystals.
Solid potassium chloride is readily soluble in water, depending on the temperature:
| Temperature | Solubility [g/L] |
|---|---|
| 0 °C | 281 |
| 10 °C | 312 |
| 20 °C | 339.7 |
| 25 °C | 355 |
| 30 °C | 372 |
| 40 °C | 402 |
| 50 °C | 431 |
A completely saturated potassium chloride solution is obtained at 20 °C by dissolving 339.7 grams of KCl in one liter of water. The boiling point of this solution is 108.6 °C, and its density is 1.18 g/cm3.
The following table shows some data and properties (molar concentration c, mass concentration β, density ρ, refractive index nD) of aqueous potassium chloride solutions as a function of the mass fraction of KCl. The values are valid for a temperature of 20 °C.
| Mass percent | c [mol/L] | β [g/L] | Molality b [mol/kg] | Density ρ [g cm-3] | Refractive Index nD |
|---|---|---|---|---|---|
| 0.5 % | 0.067 | 4.995 | 0.067 | 1.0014 | 1.3337 |
| 1 % | 0.135 | 10.064 | 0.135 | 1.0046 | 1.3343 |
| 2 % | 0.271 | 20.203 | 0.274 | 1.0110 | 1.3357 |
| 3 % | 0.409 | 30.490 | 0.415 | 1.0174 | 1.3371 |
| 4 % | 0.549 | 40.927 | 0.559 | 1.0239 | 1.3384 |
| 5 % | 0.691 | 51.513 | 0.706 | 1.0304 | 1.3398 |
| 6 % | 0.835 | 62.248 | 0.856 | 1.0369 | 1.3411 |
| 7 % | 0.980 | 73.057 | 1.010 | 1.0434 | 1.3425 |
| 8 % | 1.127 | 84.016 | 1.166 | 1.0500 | 1.3438 |
| 9 % | 1.276 | 95.124 | 1.327 | 1.0566 | 1.3452 |
| 10 % | 1.426 | 106.306 | 1.490 | 1.0633 | 1.3466 |
| 11 % | 1.579 | 117.712 | 1.658 | 1.0700 | 1.3479 |
| 12 % | 1.733 | 129.192 | 1.829 | 1.0768 | 1.3493 |
| 13 % | 1.890 | 140.896 | 2.004 | 1.0836 | 1.3507 |
| 14 % | 2.048 | 152.675 | 2.184 | 1.0905 | 1.3521 |
| 15 % | 2.208 | 164.603 | 2.367 | 1.0974 | 1.3535 |
| 16 % | 2.370 | 176.679 | 2.555 | 1.1043 | 1.3549 |
| 17 % | 2.534 | 188.905 | 2.747 | 1.1114 | 1.3563 |
| 18 % | 2.701 | 201.355 | 2.945 | 1.1185 | 1.3577 |
| 19 % | 2.869 | 213.879 | 3.147 | 1.1256 | 1.3592 |
| 20 % | 3.039 | 226.552 | 3.354 | 1.1328 | 1.3606 |
| 21 % | 3.211 | 239.375 | 3.566 | 1.1399 | 1.3622 |
| 22 % | 3.386 | 252.421 | 3.783 | 1.1474 | 1.3635 |
| 23 % | 3.562 | 265.541 | 4.007 | 1.1545 | 1.3651 |
| 24 % | 3.742 | 278.960 | 4.236 | 1.1623 | 1.3665 |
| 25 % | 3.924 | 292.528 | 4.471 | 1.1701 | 1.3679 |
Electrolyte solutions containing potassium chloride, such as Ringer´s solution, are used in medicine and contain 4 to 5 mmol/L potassium ions.
A 3 molar or 3M KCl solution (c = 3 mol/l) serves as a storage solution for many types of pH electrodes and ORP probes; the solution is obtained from 223.644 g of potassium chloride in a volumetric flask and making up the volume to one liter with distilled water.
The relative humidity above a saturated KCl solution in a container is a constant 85% at 23°C.
Potassium chloride solutions conduct electricity depending on temperature and concentration. They are used - along with other salt solutions - for calibrating conductivity meters. The electrical conductivity (conductance values κ in millisiemens per cm) of various KCl solutions are shown in the following tables.
The first table lists the conductivity of a potassium chloride solution as a function of the mass percent of KCl in the aqueous solution; all values apply to a temperature of 20 °C:
| Mass-% KCl | g/L | kappa κ [mS/cm] |
|---|---|---|
| 0.5 | 4.995 | 8.2 |
| 1 | 10.064 | 15.7 |
| 2 | 20.203 | 29.5 |
| 5 | 51.513 | 71.9 |
| 10 | 106.306 | 143 |
| 15 | 164.604 | 208 |
The second table lists typical values for preparing a calibration solution (in grams of KCl per liter of pure distilled water). The data refers to a temperature of 25 °C.
| g/L | mol/L | κ in mS/cm |
|---|---|---|
| 0 | 0 | 0.02 |
| 0.0417 | 0.00056 | 0.084 |
| 0.0745 | 0.001 | 0.700 |
| 0.7454 | 0.01 | 1.413 |
| 1.4909 | 0.02 | 2.765 |
| 2.9819 | 0.04 | 5.446 |
| 7.4548 | 0.10 | 12.880 |
| 37.2741 | 0.50 | 56.6 |
| 74.5483 | 1.00 | 111.8 |
| 110.0966 | 2.00 | 212.0 |
Mass-related elemental composition and isotope proportions of the compound Potassium chloride - ClK - calculated based on molecular mass.
*) The third column lists the atomic masses or isotope masses of the elements involved and - in square brackets - the natural isotope composition.
The molar mass is M = 74.5483 grams per mole.
The amount of substance in one kilogram of the substance is n = 13.414 mol.
The amount of substance in one gram of the substance is n = 0.013 mol.
Monoisotopic mass: 73.932559185 Da - related to 35Cl39K.
ATC Code:A12BA01
A12BA51
B05XA01
Potassium chloride is used medically to treat hypokalemia (low blood potassium) as a source of the mineral potassium. The substance is also a component of various electrolyte solutions, such as Ringer´s solution, and an additive in peritoneal dialysis solutions. An overdose can lead to hyperkalemia, which can significantly disrupt cell signaling.
For detailed information on the active ingredient, see: DrugBank DB00761.
E-Nummer: E508
Potassium chloride is an approved food additive in the EU, used as a flavor enhancer. It is primarily used in ready-made meals, spice mixes, low-sodium or reduced-calorie foods, and table salt. There is no maximum limit on the amount permitted (quantum satis).
EU: Status and regulations see EU Food Additives DB Ref. Number 3206.
INCI Name: Potassium chloride
Ingredient in cosmetics and personal care products used to regulate the viscosity of the preparation.
Source: CosIng (Cosmetic Ingredient Database) number: 36948.
The table below lists producers and suppliers of Potassium chloride as a commercial chemical for laboratories, research, industry and production with the corresponding contact details.
[0] - Specialist and research articles in scientific journals via PubMed: Potassium_chloride.
[1] - Maged Younes, Gabriele Aquilina, Laurence Castle et al.:
Re‐evaluation of hydrochloric acid (E 507), potassium chloride (E 508), calcium chloride (E 509) and magnesium chloride (E 511) as food additives.
In: EFSA Journal, (2019), DOI 10.2903/j.efsa.2019.5751.
Last update: 2026-01-07
Perma link: https://www.chemlin.org/chemical-compound/Potassium chloride.php
© 1996 - 2026 ChemLin