All atomic nuclei of the chemical element mercury are summarized under mercury isotopes; these all consist of an atomic nucleus with 80 protons and, in the uncharged state, 80 electrons. The difference between each isotope of mercury is based on the number of neutrons in the nucleus.
The natural mercury deposits on earth consist of a mix of seven different, stable isotopes with the following percentage composition:
Atomic Mass ma | Quantity | Half-life | Spin | |
Mercury Isotopic mixture | 200,592 u | 100 % | ||
Isotope 196Hg | 195,96583(2) u | 0,15(1) % | stable | 0+ |
Isotope 198Hg | 197,966769(3) u | 10,04(3) % | stable | 0+ |
Isotope 199Hg | 198,968281(3) u | 16,94(12) % | stable | 1/2- |
Isotope 200Hg | 199,968327(3) u | 23,14(9) % | stable | 0+ |
Isotope 201Hg | 200,970303(5) u | 13,17(9) % | stable | 3/2- |
Isotope 202Hg | 201,970643(5) u | 29,74(13) % | stable | 0+ |
Isotope 204Hg | 203,973494(3) u | 6,82(4) % | stable | 0+ |
Alle anderen bekannten und charakterisierten Quecksilber-Nuklide sind instabil; mit einer Halbwertszeit von 444 Jahren ist Quecksilber-194 das langlebigste Radioisotop. Technisch besitzen die künstlichen Quecksilbernuklide keinerlei Bedeutung.
Isotope Nuclide | E | N | Atomic Mass [Nuclear Mass] {Mass Excess} | Spin I (h/2π) | Parent |
---|---|---|---|---|---|
1 | 2 | 3 | 4 | 5 | 6 |
Mercury-171 | 17180Hg | 91 | 171.00374(32) u [170.9598584 u] {3.48379 MeV} | ||
Mercury-172 | 17280Hg | 92 | 171.99886(16) u [171.9549784 u] {-1.0619 MeV} | 0+ | |
Mercury-173 | 17380Hg | 93 | 172.99709(21) u [172.9532084 u] {-2.71065 MeV} | (7/2-) | |
Mercury-174 | 17480Hg | 94 | 173.992871(21) u [173.9489894 u] {-6.64062 MeV} | ||
Mercury-175 | 17580Hg | 95 | 174.99144(8) u [174.9475584 u] {-7.97359 MeV} | (7/2-) | |
Mercury-176 | 17680Hg | 96 | 175.987348(12) u [175.9434664 u] {-11.78526 MeV} | 0+ | 180Pb |
Mercury-177 | 17780Hg | 97 | 176.98628(8) u [176.9423984 u] {-12.7801 MeV} | 7/2- | |
Mercury-177m | 177m80Hg | 97 | 176.98628(8) u [176.9423984 u] {-12.7801 MeV} | 13/2+ | |
Mercury-178 | 17880Hg | 98 | 177.982484(12) u [177.9386024 u] {-16.31605 MeV} | 0+ | 182Pb |
Mercury-179 | 17980Hg | 99 | 178.981827(29) u [178.9379454 u] {-16.92804 MeV} | (7/2-) | 183Pb |
Mercury-180 | 18080Hg | 100 | 179.978260(14) u [179.9343784 u] {-20.25068 MeV} | 0+ | 184Pb |
Mercury-181 | 18180Hg | 101 | 180.977819(17) u [180.9339374 u] {-20.66147 MeV} | 1/2- | |
Mercury-182 | 18280Hg | 102 | 181.974689(11) u [181.9308074 u] {-23.57704 MeV} | 0+ | 186Pb 182Tl |
Mercury-183 | 18380Hg | 103 | 182.974445(8) u [182.9305634 u] {-23.80433 MeV} | 1/2- | 187Pb 183Tl |
Mercury-184 | 18480Hg | 104 | 183.971713(11) u [183.9278314 u] {-26.34917 MeV} | 0+ | 188Pb 184Tl |
Mercury-185 | 18580Hg | 105 | 184.971891(15) u [184.9280094 u] {-26.18336 MeV} | 1/2- | 189Pb |
Mercury-185m | 185m80Hg | 105 | 184.971891(15) u [184.9280094 u] {-26.18336 MeV} | 13/2+ | |
Mercury-186 | 18680Hg | 106 | 185.969362(13) u [185.9254804 u] {-28.53911 MeV} | 0+ | 190Pb |
Mercury-186m | 186m80Hg | 106 | 185.969362(13) u [185.9254804 u] {-28.53911 MeV} | (8-) | |
Mercury-187 | 18780Hg | 107 | 186.969814(15) u [186.9259324 u] {-28.11808 MeV} | 3/2(-) | 191Pb 187Tl |
Mercury-187m | 187m80Hg | 107 | 186.969814(15) u [186.9259324 u] {-28.11808 MeV} | 13/2(+) | |
Mercury-188 | 18880Hg | 108 | 187.967577(13) u [187.9236954 u] {-30.20183 MeV} | 0+ | 192Pb 188Tl |
Mercury-188m | 188m80Hg | 108 | 187.967577(13) u [187.9236954 u] {-30.20183 MeV} | 12+ | |
Mercury-189 | 18980Hg | 109 | 188.96819(3) u [188.9243084 u] {-29.63082 MeV} | 3/2- | 189Tl |
Mercury-189m | 189m80Hg | 109 | 188.96819(3) u [188.9243084 u] {-29.63082 MeV} | 13/2+ | |
Mercury-190 | 19080Hg | 110 | 189.966322(17) u [189.9224404 u] {-31.37085 MeV} | 0+ | 194Pb 190Tl |
Mercury-191 | 19180Hg | 111 | 190.967158(24) u [190.9232764 u] {-30.59213 MeV} | 3/2(-) | 191Tl |
Mercury-191m | 191m80Hg | 111 | 190.967158(24) u [190.9232764 u] {-30.59213 MeV} | 13/2(+) | |
Mercury-192 | 19280Hg | 112 | 191.965634(17) u [191.9217524 u] {-32.01172 MeV} | 0+ | 192Tl |
Mercury-193 | 19380Hg | 113 | 192.966653(17) u [192.9227714 u] {-31.06253 MeV} | 3/2(-) | 193Tl |
Mercury-193m | 193m80Hg | 113 | 192.966653(17) u [192.9227714 u] {-31.06253 MeV} | 13/2(+) | |
Mercury-194 | 19480Hg | 114 | 193.965449(3) u [193.9215674 u] {-32.18405 MeV} | 0+ | 194Tl |
Mercury-195 | 19580Hg | 115 | 194.966706(25) u [194.9228244 u] {-31.01316 MeV} | 1/2- | 195Tl |
Mercury-195m | 195m80Hg | 115 | 194.966706(25) u [194.9228244 u] {-31.01316 MeV} | 13/2+ | |
Mercury-196 | 19680Hg | 116 | 195.96583(2) u [195.9219484 u] {-31.82915 MeV} | 0+ | 196Tl 196Au |
Mercury-197 | 19780Hg | 117 | 196.967214(3) u [196.9233324 u] {-30.53996 MeV} | 1/2- | 197Tl |
Mercury-197m | 197m80Hg | 117 | 196.967214(3) u [196.9233324 u] {-30.53996 MeV} | 13/2+ | |
Mercury-198 | 19880Hg | 118 | 197.966769(3) u [197.9228874 u] {-30.95448 MeV} | 0+ | 198Tl 198Au 202Pb |
Mercury-199 | 19980Hg | 119 | 198.968281(3) u [198.9243994 u] {-29.54606 MeV} | 1/2- | 199Tl 199Au |
Mercury-199m | 199m80Hg | 119 | 198.968281(3) u [198.9243994 u] {-29.54606 MeV} | 13/2+ | |
Mercury-200 | 20080Hg | 120 | 199.968327(3) u [199.9244454 u] {-29.50321 MeV} | 0+ | 200Tl 200Au |
Mercury-201 | 20180Hg | 121 | 200.970303(5) u [200.9264214 u] {-27.66258 MeV} | 3/2- | 201Tl 201Au |
Mercury-201m | 201m80Hg | 121 | 200.970303(5) u [200.9264214 u] {-27.66258 MeV} | 13/2+ | |
Mercury-202 | 20280Hg | 122 | 201.970643(5) u [201.9267614 u] {-27.34587 MeV} | 0+ | 202Tl 202Au |
Mercury-203 | 20380Hg | 123 | 202.9728723(17) u [202.9289907 u] {-25.26929 MeV} | 5/2- | 203Au |
Mercury-203m | 203m80Hg | 123 | 202.9728723(17) u [202.9289907 u] {-25.26929 MeV} | ||
Mercury-204 | 20480Hg | 124 | 203.973494(3) u [203.9296124 u] {-24.69018 MeV} | 0+ | 204Tl 204Au |
Mercury-205 | 20580Hg | 125 | 204.976073(4) u [204.9321914 u] {-22.28786 MeV} | 1/2- | 205Au |
Mercury-205m | 205m80Hg | 125 | 204.976073(4) u [204.9321914 u] {-22.28786 MeV} | 13/2+ | |
Mercury-206 | 20680Hg | 126 | 205.977514(22) u [205.9336324 u] {-20.94557 MeV} | 0+ | 210Pb |
Mercury-207 | 20780Hg | 127 | 206.98230(3) u [206.9384184 u] {-16.48744 MeV} | (9/2+) | |
Mercury-208 | 20880Hg | 128 | 207.98576(3) u [207.9418784 u] {-13.26447 MeV} | 0+ | |
Mercury-209 | 20980Hg | 129 | 208.99072(16) u [208.9468384 u] {-8.64426 MeV} | (9/2+) | |
Mercury-210 | 21080Hg | 130 | 209.99424(21) u [209.9503584 u] {-5.36541 MeV} | 0+ | |
Mercury-210m1 | 210m180Hg | 130 | 209.99424(21) u [209.9503584 u] {-5.36541 MeV} | (3-) | |
Mercury-210m2 | 210m280Hg | 130 | 209.99424(21) u [209.9503584 u] {-5.36541 MeV} | (8+) | |
Mercury-211 | 21180Hg | 131 | 210.99933(21) u [210.9554484 u] {-0.6241 MeV} | ||
Mercury-212 | 21280Hg | 132 | 212.00296(32) u [211.9590784 u] {2.75722 MeV} | 0+ | |
Mercury-213 | 21380Hg | 133 | 213.00823(32) u [212.9643484 u] {7.6662 MeV} | ||
Mercury-214 | 21480Hg | 134 | 214.01200(43) u [213.9681184 u] {11.17793 MeV} | 0+ | |
Mercury-215 | 21580Hg | 135 | 215.01740(43) u [214.9735184 u] {16.208 MeV} | ||
Mercury-216 | 21680Hg | 136 | 216.02132(43) u [215.9774384 u] {19.85945 MeV} | 0+ |
Isotope | Radioactive Decay | Extern | |||
---|---|---|---|---|---|
Half-life | Decay Mode | Probability | Energy | ||
7 | 8 | 9 | 10 | 11 | 12 |
Hg-171 | 59 μs | α → 167Pt | ca. 100 % | 7.668(15) MeV | AL |
Hg-172 | 231(9) μs | α → 168Pt | ca. 100 % | 7.524(6) MeV | AL |
Hg-173 | 0.80(8) ms | α → 169Pt | 100 % | 7.378(4) MeV | AL |
Hg-174 | 2.1 ms | α → 170Pt | 99.6(4) % | 7.233(6) MeV | AL |
Hg-175 | 10.6(4) ms | α → 171Pt | 100 % | 7.072(5) MeV | AL |
Hg-176 | 20.3(14) ms | α → 172Pt | 94(12) % | 6.897(6) MeV | AL |
Hg-177 | 0.117(7) s | α → 173Pt | 100 % | 6.74(5) MeV | AL |
Hg-177m | 1.50(15) μs | Iso → 177Hg | 100 % | ||
Hg-178 | 266.5(24) ms | α → 174Pt EC/β+ → 178Au | ca. 70 % ca. 30 % | 6.577(3) MeV 5.988(15) MeV | AL |
Hg-179 | 1.05(3) s | α → 175Pt EC/β+ → 179Au EC, p → 178Pt | 55(25) % 45(25) % ca. 0.15 % | 6.36(3) MeV 8.06(3) MeV ? | AL |
Hg-180 | 2.59(1) s | α → 176Pt EC/β+ → 180Au | 48(2) % 52(2) % | 6.2585(24) MeV 5.375(14) MeV | AL |
Hg-181 | 3.6(1) s | α → 177Pt EC/β+ → 181Au EC, p → 180Pt EC, α → 177Ir | 27(2) % 73(2) % 0.013(3) % Spuren | 6.284(4) MeV 7.210(25) MeV | AL |
Hg-182 | 10.83(6) s | α → 178Pt EC/β+ → 182Au | 13.8(9) % 86.2(9) % | 5.996(5) MeV 4.724(23) MeV | AL |
Hg-183 | 9.4(7) s | α → 179Pt EC/β+ → 183Au EC, p → 182Pt | 11.7(20) % 88.3(20) % 0.00026 % | 6.039(4) MeV 6.387(12) MeV | AL |
Hg-184 | 30.87(26) s | α → 180Pt EC/β+ → 184Au | 1.11(6) % 90.89(6) % | 5.662(4) MeV 3.970(24) MeV | AL |
Hg-185 | 49.1(10) s | α → 181Pt EC/β+ → 185Au | 6(1) % 94(1) % | 5.773(4) MeV 5.674(14) MeV | AL |
Hg-185m | 21.6(15) s | α → 181Pt EC/β+ → 185Au Iso → 185Hg | ca. 0.03 % 46(10) % 54(10) % | ||
Hg-186 | 1.38(6) min | α → 182Pt EC/β+ → 186Au | 0.016(5) % 99.984(5) % | 5.204(10) MeV 3.176(24) MeV | AL |
Hg-186m | 82(5) μs | ||||
Hg-187 | 1.9(3) min | α → 183Pt EC/β+ → 187Au | < 0.00037 % > 99.9996 % | 5.230(14) MeV 4.910(26) MeV | AL |
Hg-187m | 2.4(3) min | α → 183Pt EC/β+ → 187Au | Spuren >> 99 % | ||
Hg-188 | 3.25(15) min | α → 184Pt EC/β+ → 188Au | Spuren > 99.9999 % | 4.707(16) MeV 2.169(13) MeV | AL |
Hg-188m | 154(20) ns | ||||
Hg-189 | 7.6(2) min | α → 185Pt EC/β+ → 189Au | < 0.00003 % > 99.9999 % | 4.640(40) MeV 3.960(40) MeV | AL |
Hg-189m | 8.6(2) min | α → 185Pt EC/β+ → 189Au | < 0.00003 % > 99.9999 % | ||
Hg-190 | 20.0(5) min | α → 186Pt EC/β+ → 190Au | Spuren > 99.9999 % | 4.069(27) MeV 1.463(16) MeV | AL |
Hg-191 | 49(10) min | EC/β+ → 191Au | 100 % | 3.206(23) MeV | AL |
Hg-191m | 50.8(15) min | EC/β+ → 191Au | 100 % | ||
Hg-192 | 4.85(20) h | EC → 192Au | 100 % | 0.761(22) MeV | AL |
Hg-193 | 3.80(15) h | EC/β+ → 193Au | 100 % | 2.343(18) MeV | AL |
Hg-193m | 11.8(2) h | EC/β+ → 193Au Iso → 193Hg | 92.8(5) % 7.2(5) % | ||
Hg-194 | 444(77) a | EC → 194Au | 100 % | 28(4) MeV | AL |
Hg-195 | 10.53(3) h | EC/β+ → 195Au | 100 % | 1.554(23) MeV | AL |
Hg-195m | 41.6(8) h | EC/β+ → 195Au Iso → 195Hg | 45.8(20) % 54.2(20) % | ||
Hg-196 | stable | AL | |||
Hg-197 | 64.14(5) h | EC → 197Au | 100 % | 0.600(3) MeV | AL |
Hg-197m | 23.8(1) h | EC/β+ → 197Au Iso → 197Hg | 8.6(7) % 91.4(7) % | ||
Hg-198 | stable | AL | |||
Hg-199 | stable | AL | |||
Hg-199m | 42.67(9) min | Iso → 199Hg | 100 % | ||
Hg-200 | stable | AL | |||
Hg-201 | stable | AL | |||
Hg-201m | 94(2) μs | Iso → 201Hg | 100 % | ||
Hg-202 | stable | AL | |||
Hg-203 | 46.594(12) d | β- → 203Tl | 100 % | 0.4921(12) MeV | AL |
Hg-203m | 24(4) μs | Iso → 203Hg | 100 % | ||
Hg-204 | stable | AL | |||
Hg-205 | 5.14(9) min | β- → 205Tl | 100 % | 1.533(4) MeV | AL |
Hg-205m | 1.09(4) ms | Iso → 205Hg | 100 % | ||
Hg-206 | 8.32(7) min | β- → 206Tl | 100 % | 1.308(20) MeV | AL |
Hg-207 | 2.9(2) min | β- → 207Tl | 100 % | 4.55(3) MeV | AL |
Hg-208 | 41(5) min | β- → 208Tl | 100 % | 3.48(3) MeV | AL |
Hg-209 | 36 s | β- → 209Tl | 100 % | 5.00(15) MeV | AL |
Hg-210 | AL | ||||
Hg-210m1 | 2.1(7) μs | Iso → 210Hg | 100 % | ||
Hg-210m2 | 2(1) μs | Iso → 210Hg | 100 % | ||
Hg-211 | 300 ns | β- → 211Tl β-, n → 210Tl | ? ? | 5.45(20) MeV 0.55(20) MeV | AL |
Hg-212 | 300 ns | β- → 212Tl β-, n → 211Tl | ? ? | 4.31(36) MeV 0.76(30) MeV | AL |
Hg-213 | 300 ns | β- → 213Tl β-, n → 212Tl | ? ? | 5.88(30) MeV 1.15(36) MeV | AL |
Hg-214 | > 300 ns | β- → 214Tl β-, n → 213Tl | ? ? | 4.71(45) MeV 1.32(40) MeV | AL |
Hg-215 | > 300 ns | β- → 215Tl β-, n → 214Tl | ? ? | 6.30(50) MeV 1.67(45) MeV | AL |
Hg-216 | > 300 ns | β- → 216Tl β-, n → 215Tl | ? ? | 5.14(50) MeV 1.88(50) MeV | AL |
Notes (related to the columns):
1 - name of the nuclide, isotope.
2 - E: isotope symbol with mass number (superscript; number of nucleons) and Atomic number (subscript; number of protons).
3 - N: number of neutrons.
4 - relative atomic mass of the Mercury isotope (isotopic mass including electrons) and the mass of the atomic nucleus in square brackets (nuclear mass, nuclide mass without electrons), each related to 12C = 12.00000 [2]. In addition, the mass excess is given in MeV.
5 - nuclear spin I, unit: h/2π.
6 - source nuclides: Possible, assumed or actual source nuclides (mother nuclides, parent nuclides). If applicable, the corresponding decay modes can be found in the data for the respective starting nuclide.
7 - isotope notation in short form.
8 - decay: half-live of the Mercury isotope (a = years; ; d = days; h = hours; min = minutes; s = seconds).
9 - decay mode: type of decay into the respective daughter nuclides with n = neutron emission; p = proton emission; α = alpha decay; β- = beta minus decay with electron emission; EC = electron capture; β+ = positron emission; ε = β+ and/or EC; Iso = isomeric transition; CD = cluster decay; SF = spontaneous decay.
10 - decay probability in percent (%).
11 - decay energy; Particle energy related to decay type.
12 - other information and notes: AL = Adopted Levels (link to external data [1]).
Miscellaneous:
()- Numbers in brackets: uncertainty to represent the spread of the reported value.
~ - Theoretical values or systematic trends.
- unlisted-: Nuclides that have already been mentioned in the literature but for some reason can no longer be found in the current nuclide tables because their discovery e.g. has not confirmed.
Nuclide quantity 1) spin | Nuclear magnetic moment μ/μN | Gyromagnetic ratio {Quadrupole moment} | Resonant frequency v0 bei 1 T | Relative sensitivity H0 = const. v0 = const. 3) |
---|---|---|---|---|
199Hg 16,94(12) % 1/2- | + 0,5058855(9) | 4,8458 {} | 7,7123 | 0,00594 0,1811 |
201Hg 13,17(9) % 3/2- | - 0,5602257(14) | - 1,7888 {+ 0,387(6)} | 2,8469 | 0,00149 0,3343 |
1) Quantity Percentage of natural occurrence.
2) Gyromagnetic ratio: 107 rad T-1 s-1
Quadrupole moment: Q [barn] = [100 fm2]
3) Related to 1H = 1,000.
According to the Radiation Protection Ordinance (StrlSchV 2018, Germany), the following values (columns 1 to 7) apply to the handling of Mercury radionuclides:
Nuclide | Limit Value | HASS limit | SC | Daughter Nuclides | Half-life | |
---|---|---|---|---|---|---|
Hg-193+ | 106 Bq | 100 Bq/g | 3.8 h | |||
Hg-193m+ | 106 Bq | 10 Bq/g | 11.8 h | |||
Hg-194+ | 106 Bq | 0,1 Bq/g | 0,07 TBq | Au-194 | 444.0 a | |
Hg-195+ | 106 Bq | 100 Bq/g | 9.9 h | |||
Hg-195m+ | 106 Bq | 100 Bq/g | 0,2 TBq | Hg-195 | 41.6 h | |
Hg-197 | 107 Bq | 100 Bq/g | 2 TBq | 10 Bq cm-2 | 64.6 h | |
Hg-197m+ | 106 Bq | 100 Bq/g | 0,7 TBq | 10 Bq cm-2 | 23.8 h | |
Hg-203 | 105 Bq | 100 Bq/g | 0,3 TBq | 10 Bq cm-2 | 46.6 d |
(HASS = High-Activity Sealed Radioactive Sources; SC = surface contamination)
Properties of the Mercury nucleides
[1] - NuDat: National Nuclear Data Center, Brookhaven National Laboratory, based on ENSDF and the Nuclear Wallet Cards.
[2] - G. Audi et. al.: The NUBASE evaluation of nuclear and decay properties. Nuclear Physics, (2003), DOI 10.1016/j.nuclphysa.2003.11.001.
[3] - Live Chart of Nuclides. Nuclear structure and decay data.
Mercury: NMR properties - 199Hg-NMR, 201Hg-NMR
[4] - N. J. Stone: Table of nuclear magnetic dipole and electric quadrupole moments. Atomic Data and Nuclear Data Tables, (2005), DOI 10.1016/j.adt.2005.04.001.
[5] - Pekka Pyykkö: Year-2008 nuclear quadrupole moments. Molecular Physics, (2008), DOI 10.1080/00268970802018367.
[6] - Pekka Pyykkö: Year-2017 nuclear quadrupole moments. Molecular Physics, (2018), DOI 10.1080/00268976.2018.1426131.
[7] - N. J. Stone: Table of recommended nuclear magnetic dipole moments. IAEA, (2019).
More sources:
[8] - Isotopic abundances, atomic weights and isotopic masses: see respective keyword.
[9] - Bridget A. Bergquist, Joel D. Blum:
The Odds and Evens of Mercury Isotopes: Applications of Mass-Dependent and Mass-Independent Isotope Fractionation.
In: Elements, (2009), DOI 10.2113/gselements.5.6.353.
[10] - Jeroen E. Sonkea, Joel D. Blum:
Advances in mercury stable isotope biogeochemistry.
In: Chemical Geology, (2012), DOI 10.1016/j.chemgeo.2012.10.035.
[11] - M. Warda, A. Staszczak, W. Nazarewicz:
Fission modes of mercury isotopes.
In: Physical Review C, (2012), DOI 10.1103/PhysRevC.86.024601.
[12] - Jason D. Demers, Joel D. Blum, Donald R. Zak:
Mercury isotopes in a forested ecosystem: implications for air-surface exchange dynamics and the global mercury cycle.
In: Global Biogeochemical Cycles, (2013), DOI 10.1002/gbc.20021.
Last update: 2022-12-12
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