More Chemistry
All atomic nuclei of the chemical element polonium are summarized under polonium isotopes; these all consist of an atomic nucleus with 84 protons and, in the uncharged state, 84 electrons. The difference between each polonium isotope is based on the number of neutrons in the nucleus.
The known nuclides of the chemical element polonium are all unstable and therefore radioactive; the artificial nuclide polonium-209 has the longest lifetime with a half-life of 103 years.
Natural polonium deposits consist of 99.998% of the isotope 210Po; in addition, the isotopes Po-211, 212, 214, 215, 216 and 218 occur in traces.
209Po and 208Po are replaced by α-proton or deuteron bombardment of lead or bismuth in a cyclotron.
Isotope Nuclide | E | N | Atomic Mass [Nuclear Mass] {Mass Excess} | Spin I (h/2π) | Parent |
---|---|---|---|---|---|
1 | 2 | 3 | 4 | 5 | 6 |
Polonium-186 | 18684Po | 102 | 186.004403(20) u [185.9583277 u] {4.10137 MeV} | 0+ | |
Polonium-187 | 18784Po | 103 | 187.00304(3) u [186.9569647 u] {2.83174 MeV} | (1/2-,5/2-) | |
Polonium-188 | 18884Po | 104 | 187.999416(21) u [187.9533407 u] {-0.54399 MeV} | 0+ | |
Polonium-189 | 18984Po | 105 | 188.998473(24) u [188.9523977 u] {-1.42239 MeV} | (5/2-) | |
Polonium-190 | 19084Po | 106 | 189.995101(14) u [189.9490257 u] {-4.56339 MeV} | 0+ | |
Polonium-191 | 19184Po | 107 | 190.994558(8) u [190.9484827 u] {-5.06919 MeV} | (3/2-) | 195Rn |
Polonium-191m | 191m84Po | 107 | 190.994558(8) u [190.9484827 u] {-5.06919 MeV} | (13/2+) | |
Polonium-192 | 19284Po | 108 | 191.991336(12) u [191.9452607 u] {-8.07046 MeV} | 0+ | 196Rn |
Polonium-192m | 192m84Po | 108 | 191.991336(12) u [191.9452607 u] {-8.07046 MeV} | (11-) | |
Polonium-193 | 19384Po | 109 | 192.991062(16) u [192.9449867 u] {-8.32569 MeV} | (3/2-) | 197Rn |
Polonium-193m | 193m84Po | 109 | 192.991062(16) u [192.9449867 u] {-8.32569 MeV} | (13/2+) | |
Polonium-194 | 19484Po | 110 | 193.988186(14) u [193.9421107 u] {-11.00467 MeV} | 0+ | 198Rn |
Polonium-194m | 194m84Po | 110 | 193.988186(14) u [193.9421107 u] {-11.00467 MeV} | (11-) | |
Polonium-195 | 19584Po | 111 | 194.98813(4) u [194.9420547 u] {-11.05683 MeV} | (3/2-) | 199Rn |
Polonium-195m | 195m84Po | 111 | 194.98813(4) u [194.9420547 u] {-11.05683 MeV} | (13/2+) | |
Polonium-196 | 19684Po | 112 | 195.985536(15) u [195.9394607 u] {-13.47313 MeV} | 0+ | 200Rn |
Polonium-196m | 196m84Po | 112 | 195.985536(15) u [195.9394607 u] {-13.47313 MeV} | 11- | |
Polonium-197 | 19784Po | 113 | 196.98566(5) u [196.9395847 u] {-13.35762 MeV} | (3/2-) | 201Rn 197At |
Polonium-197m | 197m84Po | 113 | 196.98566(5) u [196.9395847 u] {-13.35762 MeV} | (13/2+) | |
Polonium-198 | 19884Po | 114 | 197.983389(19) u [197.9373137 u] {-15.47305 MeV} | 0+ | 202Rn |
Polonium-198m1 | 198m184Po | 114 | 197.983389(19) u [197.9373137 u] {-15.47305 MeV} | 11- | |
Polonium-198m2 | 198m284Po | 114 | 197.983389(19) u [197.9373137 u] {-15.47305 MeV} | 12+ | |
Polonium-199 | 19984Po | 115 | 198.983673(19) u [198.9375977 u] {-15.2085 MeV} | (3/2-) | 203Rn |
Polonium-199m | 199m84Po | 115 | 198.983673(19) u [198.9375977 u] {-15.2085 MeV} | (13/2+) | |
Polonium-200 | 20084Po | 116 | 199.981812(8) u [199.9357367 u] {-16.94201 MeV} | 0+ | 204Rn 200At |
Polonium-201 | 20184Po | 117 | 200.982264(5) u [200.9361887 u] {-16.52098 MeV} | 3/2- | 205Rn 201At |
Polonium-201m | 201m84Po | 117 | 200.982264(5) u [200.9361887 u] {-16.52098 MeV} | 13/2+ | |
Polonium-202 | 20284Po | 118 | 201.980739(9) u [201.9346637 u] {-17.94151 MeV} | 0+ | 206Rn 202At |
Polonium-203 | 20384Po | 119 | 202.981416(9) u [202.9353407 u] {-17.31088 MeV} | 5/2- | 207Rn 203At |
Polonium-203m1 | 203m184Po | 119 | 202.981416(9) u [202.9353407 u] {-17.31088 MeV} | 13/2+ | |
Polonium-203m2 | 203m284Po | 119 | 202.981416(9) u [202.9353407 u] {-17.31088 MeV} | ||
Polonium-204 | 20484Po | 120 | 203.980310(12) u [203.9342347 u] {-18.34112 MeV} | 0+ | 208Rn 204At |
Polonium-204m | 204m84Po | 120 | 203.980310(12) u [203.9342347 u] {-18.34112 MeV} | 8+ | |
Polonium-205 | 20584Po | 121 | 204.981190(11) u [204.9351147 u] {-17.5214 MeV} | 5/2- | 209Rn 205At |
Polonium-205m1 | 205m184Po | 121 | 204.981190(11) u [204.9351147 u] {-17.5214 MeV} | 1/2- | |
Polonium-205m2 | 205m284Po | 121 | 204.981190(11) u [204.9351147 u] {-17.5214 MeV} | 13/2+ | |
Polonium-205m3 | 205m384Po | 121 | 204.981190(11) u [204.9351147 u] {-17.5214 MeV} | 19/2- | |
Polonium-205m4 | 205m484Po | 121 | 204.981190(11) u [204.9351147 u] {-17.5214 MeV} | 29/2- | |
Polonium-206 | 20684Po | 122 | 205.980474(4) u [205.9343987 u] {-18.18835 MeV} | 0+ | 210Rn 206At |
Polonium-206m1 | 206m184Po | 122 | 205.980474(4) u [205.9343987 u] {-18.18835 MeV} | 8+ | |
Polonium-206m2 | 206m284Po | 122 | 205.980474(4) u [205.9343987 u] {-18.18835 MeV} | 9- | |
Polonium-207 | 20784Po | 123 | 206.981593(7) u [206.9355177 u] {-17.14601 MeV} | 5/2- | 211Rn 207At |
Polonium-207m1 | 207m184Po | 123 | 206.981593(7) u [206.9355177 u] {-17.14601 MeV} | 1/2- | |
Polonium-207m2 | 207m284Po | 123 | 206.981593(7) u [206.9355177 u] {-17.14601 MeV} | 13/2+ | |
Polonium-207m3 | 207m384Po | 123 | 206.981593(7) u [206.9355177 u] {-17.14601 MeV} | 19/2- | |
Polonium-208 | 20884Po | 124 | 207.9812456(19) u [207.9351703 u] {-17.46961 MeV} | 0+ | 212Rn 208At |
Polonium-208m | 208m84Po | 124 | 207.9812456(19) u [207.9351703 u] {-17.46961 MeV} | 8+ | |
Polonium-209 | 20984Po | 125 | 208.9824304(19) u [208.9363551 u] {-16.36598 MeV} | 1/2- | 213Rn 209At |
Polonium-209m | 209m84Po | 125 | 208.9824303(19) u [208.936355 u] {-16.36607 MeV} | 31/2- | |
Polonium-210 | 21084Po | 126 | 209.9828736(12) u [209.9367983 u] {-15.95314 MeV} | 0+ | 214Rn 210At 210Bi |
Polonium-210m | 210m84Po | 126 | 209.9828736(12) u [209.9367983 u] {-15.95314 MeV} | 16+ | |
Polonium-211 | 21184Po | 127 | 210.9866531(13) u [210.9405778 u] {-12.43256 MeV} | 9/2+ | 215Rn 211At 211Bi |
Polonium-211m1 | 211m184Po | 127 | 210.9866531(13) u [210.9405778 u] {-12.43256 MeV} | (25/2+) | |
Polonium-211m2 | 211m284Po | 127 | 210.9866531(13) u [210.9405778 u] {-12.43256 MeV} | (31/2-) | |
Polonium-211m3 | 211m384Po | 127 | 210.9866531(13) u [210.9405778 u] {-12.43256 MeV} | (43/2+) | |
Polonium-212 | 21284Po | 128 | 211.9888679(12) u [211.9427926 u] {-10.36948 MeV} | 0+ | 216Rn 212Bi |
Polonium-212m | 212m84Po | 128 | 211.9888679(12) u [211.9427926 u] {-10.36948 MeV} | (18+) | |
Polonium-213 | 21384Po | 129 | 212.992857(3) u [212.9467817 u] {-6.65366 MeV} | 9/2+ | 217Rn 213Bi |
Polonium-214 | 21484Po | 130 | 213.9952012(16) u [213.9491259 u] {-4.47005 MeV} | 0+ | 218Rn 214Bi |
Polonium-215 | 21584Po | 131 | 214.9994185(23) u [214.9533432 u] {-0.54166 MeV} | 9/2+ | 219Rn 215Bi |
Polonium-216 | 21684Po | 132 | 216.0019135(19) u [215.9558382 u] {1.78241 MeV} | 0+ | 220Rn 216Bi |
Polonium-217 | 21784Po | 133 | 217.006316(7) u [216.9602407 u] {5.88332 MeV} | (9/2+) | 221Rn 217Bi |
Polonium-218 | 21884Po | 134 | 218.0089712(21) u [217.9628959 u] {8.35662 MeV} | 0+ | 222Rn 218Bi |
Polonium-219 | 21984Po | 135 | 219.013614(17) u [218.9675387 u] {12.68136 MeV} | (9/2+) | |
Polonium-220 | 22084Po | 136 | 220.016386(19) u [219.9703107 u] {15.26346 MeV} | 0+ | |
Polonium-221 | 22184Po | 137 | 221.021228(21) u [220.9751527 u] {19.77375 MeV} | ||
Polonium-222 | 22284Po | 138 | 222.02414(4) u [221.9780647 u] {22.48627 MeV} | 0+ | |
Polonium-223 | 22384Po | 139 | 223.02907(21) u [222.9829947 u] {27.07853 MeV} | ||
Polonium-224 | 22484Po | 140 | 224.03211(21) u [223.9860347 u] {29.91027 MeV} | 0+ | |
Polonium-225 | 22584Po | 141 | 225.03707(32) u [224.9909947 u] {34.53048 MeV} | ||
Polonium-226 | 22684Po | 142 | 226.04031(43) u [225.9942347 u] {37.54852 MeV} | 0+ | |
Polonium-227 | 22784Po | 143 | 227.04539(43) u [226.9993147 u] {42.28051 MeV} |
Isotope | Radioactive Decay | Extern | |||
---|---|---|---|---|---|
Half-life | Decay Mode | Probability | Energy | ||
7 | 8 | 9 | 10 | 11 | 12 |
Po-186 | 28 μs | α → 182Pb | ~ 100 % | 8.501(14) MeV | |
Po-187 | 1.40(25) ms | α → 183Pb | ~100 % | 7.979(15) MeV | AL |
Po-188 | 0.27(3) ms | α → 184Pb | ~100 % | 8.082(15) MeV | AL |
Po-189 | 3.5(5) ms | α → 185Pb | ~100 % | 7.694(15) MeV | AL |
Po-190 | 2.46(5) ms | α → 186Pb | 100 % | 7.693(7) MeV | AL |
Po-191 | 22(1) ms | α → 187Pb | 99.0(10) % | 7.493(5) MeV | AL |
Po-191m | 93(3) ms | α → 187Pb | 96(4) % | AL | |
Po-192 | 32.2(3) ms | α → 188Pb EC/β+ → 192Bi | ca. 99.5 % ca. 0.5 % | 7.230(3) MeV 5.46(3) MeV | AL |
Po-192m | 0.58(10) μs | Iso → 192Po | 100 % | ||
Po-193 | 0.399(34) s | α → 189Pb | ≤ 100 % | 7.094(4) MeV | AL |
Po-193m | 245(22) ms | α → 189Pb | ≤ 100 % | AL | |
Po-194 | 0.392(4) s | α → 190Pb EC/β+ → 194Bi | ca. 100 % ? | 6.987(3) MeV 5.024(14) MeV | AL |
Po-194m | 15(2) μs | ||||
Po-195 | 4.64(9) s | α → 191Pb EC/β+ → 195Bi | 94(4) % 6(4) % | 6.7499(28) MeV 6.97(4) MeV | AL |
Po-195m | 1.92(2) s | α → 191Pb EC/β+ → 195Bi Iso → 195Po | ca. 90 % ca. 10 % < 0.01 % | AL | |
Po-196 | 5.8(2) s | α → 192Pb EC/β+ → 196Bi | ca. 98 % ca. 2 % | 6.6581(24) MeV 4.536(28) MeV | AL |
Po-196m | 856(17) ns | Iso → 196Po | |||
Po-197 | 84(16) s | α → 193Pb EC/β+ → 197Bi | 44(7) % 56(7) % | 6.412(3) MeV 6.33(5) MeV | AL |
Po-197m | 32(2) s | α → 193Pb EC/β+ → 197Bi Iso → 197Po | 84(9) % 16(9) % 0.01 % | AL | |
Po-198 | 1.760(24) min | α → 194Pb EC/β+ → 198Bi | 57(2) % 43(2) % | 6.3097(14) MeV 3.90(3) MeV | AL |
Po-198m1 | 200(20) ns | ||||
Po-198m2 | 0.75(5) μs | ||||
Po-199 | 5.47(15) min | α → 195Pb EC/β+ → 199Bi | 7.5(3) % 92.5(3) % | 6.0743(19) MeV 5.589(21) MeV | AL |
Po-199m | 4.17(5) min | α → 195Pb EC/β+ → 199Bi Iso → 199Po | 24(1) % 73.5(10) % 2.5(10) % | AL | |
Po-200 | 11.51(8) min | α → 196Pb EC/β+ → 200Bi | 11.1(3) % 88.9(3) % | 5.9816(18) MeV 3.429(24) MeV | AL |
Po-201 | 15.6(1) min | α → 197Pb EC/β+ → 201Bi | 1.13(3) % 98.87(3) % | 5.7993(17) MeV 4.895(16) MeV | AL |
Po-201m | 8.96(12) min | α → 197Pb EC/β+ → 201Bi Iso → 201Po | 2.4(5) % 41.4(7) % 56.2(12) % | AL | |
Po-202 | 44.6(4) min | α → 198Pb EC/β+ → 202Bi | 1.92(7) % 98.08(7) % | 5.7010(17) MeV 2.800(18) MeV | AL |
Po-203 | 36.7(5) min | α → 199Pb EC/β+ → 203Bi | 0.11(2) % 99.89(2) % | 5.496(5) MeV 4.214(15) MeV | AL |
Po-203m1 | 45(2) s | Iso → 203Po EC/β+ → 203Bi | ca. 100 % ? | AL | |
Po-203m2 | 200 ns | ||||
Po-204 | 3.519(12) h | α → 200Pb EC/β+ → 204Bi | 0.67(3) % 99.33(3) % | 5.4849(14) MeV 2.305(14) MeV | AL |
Po-204m | |||||
Po-205 | 1.74(8) h | α → 201Pb EC/β+ → 205Bi | 0.04(1) % 99.96(1) % | 5.325(10) MeV 3.544(11) MeV | AL |
Po-205m1 | 310(60) ns | ||||
Po-205m2 | 0.645(20) ms | Iso → 205Po | 100 % | AL | |
Po-205m3 | 57.4(9) ms | Iso → 205Po | 100 % | AL | |
Po-205m4 | 115(10) ns | ||||
Po-206 | 8.8(1) d | α → 202Pb EC/β+ → 206Bi | 5.45(5) % 94.55(5) % | 5.3270(13) MeV 1.840(9) MeV | AL |
Po-206m1 | 232(4) ns | ||||
Po-206m2 | 1.05(6) μs | ||||
Po-207 | 5.80(2) h | α → 203Pb EC/β+ → 207Bi | 0.021(2) % 99.979(2) % | 5.2159(25) MeV 2.909(7) MeV | AL |
Po-207m1 | 205(10) ns | ||||
Po-207m2 | 49(4) μs | ||||
Po-207m3 | 2.79(8) s | Iso → 207Po | 100 % | AL | |
Po-208 | 2.898(2) a | α → 204Pb EC/β+ → 208Bi | 99.9960(4) % 0.0040(4) % | 5.2154(13) MeV 1.4006(29) MeV | AL |
Po-208m | 350(20) ns | ||||
Po-209 | 124(3) a | α → 205Pb EC/β+ → 209Bi | 99.546(7) % 0.454(7) % | 4.9792(14) MeV 1.8926(22) MeV | AL |
Po-209n | 119(4) ns | ||||
Po-210 | 138.376(2) d | α → 206Pb | 100 % | 5.40753(7) MeV | AL |
Po-210m | 263(5) ns | ||||
Po-211 | 0.516(3) s | α → 207Pb | 100 % | 7.5946(5) MeV | AL |
Po-211m1 | 25.2(6) s | α → 207Pb Iso → 211Po | 99.984(4) % 0.016(4) % | AL | |
Po-211m2 | 243(21) ns | Iso → 211Po | 100 % | ||
Po-211m3 | 2.8(7) μs | Iso → 211Po | 100 % | ||
Po-212 | 0.299(2) μs | α → 208Pb | 100 % | 8.95420(11) MeV | AL |
Po-212m | 45.1(6) s | α → 208Pb Iso → 212Po | 99.93(2) % 0.07(2) % | AL | |
Po-213 | 3.72(2) μs | α → 209Pb | 100 % | 8.5361(26) MeV | AL |
Po-214 | 164.3(20) μs | α → 210Pb | 100 % | 7.83354(6) MeV | AL |
Po-215 | 1.781(4) ms | α → 211Pb β- → 215At | 99.99977(2) % 0.00023(2) % | 7.5263(8) MeV 0.714(7) MeV | AL |
Po-216 | 0.145(2) s | α → 212Pb | 100 % | 6.9063(5) MeV | AL |
Po-217 | 1.53(5) s | α → 213Pb β- → 217At | > 95 % < 5 % | 6.6621(23) MeV 1.489(8) MeV | AL |
Po-218 | 3.097(12) min | α → 214Pb β- → 218At | 99.980(2) % 0.020(2) % | 6.11475(9) MeV 0.256(12) MeV | AL |
Po-219 | 620(59) s | β- → 219At α → 215Pb | 71.8(20) % 28.2(20) % | 2.285(16) MeV 5.91(5) MeV | AL |
Po-220 | 300 ns | β- → 220At | ? | 0.888(23) MeV | AL |
Po-221 | 112 s | β- → 221At | ? | 2.991(24) MeV | AL |
Po-222 | 550(430) s | β- ? | AL | ||
Po-223 | 300 ns | β- → 223At | ? | 3.65(20) MeV | AL |
Po-224 | 300 ns | β- → 224At | ? | 2.2(2) MeV | AL |
Po-225 | 300 ns | β- → 225At | ? | 4.14(42) MeV | AL |
Po-226 | 300 ns | β- → 226At | ? | 2.93(50) MeV | AL |
Po-227 | 300 ns | β- → 227At | ? | 4.8(5) MeV | AL |
Notes (related to the columns):
1 - name of the nuclide, isotope.
2 - E: isotope symbol with mass number (superscript; number of nucleons) and Atomic number (subscript; number of protons).
3 - N: number of neutrons.
4 - relative atomic mass of the Polonium isotope (isotopic mass including electrons) and the mass of the atomic nucleus in square brackets (nuclear mass, nuclide mass without electrons), each related to 12C = 12.00000 [2]. In addition, the mass excess is given in MeV.
5 - nuclear spin I, unit: h/2π.
6 - source nuclides: Possible, assumed or actual source nuclides (mother nuclides, parent nuclides). If applicable, the corresponding decay modes can be found in the data for the respective starting nuclide.
7 - isotope notation in short form.
8 - decay: half-live of the Polonium isotope (a = years; ; d = days; h = hours; min = minutes; s = seconds).
9 - decay mode: type of decay into the respective daughter nuclides with n = neutron emission; p = proton emission; α = alpha decay; β- = beta minus decay with electron emission; EC = electron capture; β+ = positron emission; ε = β+ and/or EC; Iso = isomeric transition; CD = cluster decay; SF = spontaneous decay.
10 - decay probability in percent (%).
11 - decay energy; Particle energy related to decay type.
12 - other information and notes: AL = Adopted Levels (link to external data [1]).
Miscellaneous:
()- Numbers in brackets: uncertainty to represent the spread of the reported value.
~ - Theoretical values or systematic trends.
- unlisted-: Nuclides that have already been mentioned in the literature but for some reason can no longer be found in the current nuclide tables because their discovery e.g. has not confirmed.
Nuclide quantity 1) spin | Nuclear magnetic moment μ/μN | Gyromagnetic ratio {Quadrupole moment} | Resonant frequency v0 bei 1 T | Relative sensitivity H0 = const. v0 = const. 3) |
---|---|---|---|---|
209Po Spuren 1/2- | + 0,68(8) | 7,4 {} | 11,7 | 0,02096 0,2757 |
1) Quantity Percentage of natural occurrence.
2) Gyromagnetic ratio: 107 rad T-1 s-1
Quadrupole moment: Q [barn] = [100 fm2]
3) Related to 1H = 1,000.
According to the Radiation Protection Ordinance (StrlSchV 2018, Germany), the following values (columns 1 to 7) apply to the handling of Polonium radionuclides:
Nuclide | Limit Value | HASS limit | SC | Daughter Nuclides | Half-life | |
---|---|---|---|---|---|---|
Po-203 | 106 Bq | 1 Bq cm-2 | 1 Bq/cm2 | 36.7 min | ||
Po-205 | 106 Bq | 10 Bq/g | 1 Bq cm-2 | 1.7 h | ||
Po-206 | 106 Bq | 10 Bq/g | 8.8 d | |||
Po-207 | 106 Bq | 10 Bq/g | 1 Bq cm-2 | 5.8 h | ||
Po-208 | 104 Bq | 1 Bq/g | 2.9 a | |||
Po-209 | 104 Bq | 1 Bq/g | 102.0 a | |||
Po-210 | 104 Bq | 1 Bq/g | 0,06 TBq | 1 Bq cm-2 | 138.4 d |
(HASS = High-Activity Sealed Radioactive Sources; SC = surface contamination)
Properties of the Polonium nucleides
[1] - NuDat: National Nuclear Data Center, Brookhaven National Laboratory, based on ENSDF and the Nuclear Wallet Cards.
[2] - G. Audi et. al.: The NUBASE evaluation of nuclear and decay properties. Nuclear Physics, (2003), DOI 10.1016/j.nuclphysa.2003.11.001.
[3] - Live Chart of Nuclides. Nuclear structure and decay data.
Polonium: NMR properties - 209Po-NMR
[4] - N. J. Stone: Table of nuclear magnetic dipole and electric quadrupole moments. Atomic Data and Nuclear Data Tables, (2005), DOI 10.1016/j.adt.2005.04.001.
[5] - Pekka Pyykkö: Year-2008 nuclear quadrupole moments. Molecular Physics, (2008), DOI 10.1080/00268970802018367.
[6] - Pekka Pyykkö: Year-2017 nuclear quadrupole moments. Molecular Physics, (2018), DOI 10.1080/00268976.2018.1426131.
[7] - N. J. Stone: Table of recommended nuclear magnetic dipole moments. IAEA, (2019).
More sources:
[8] - Isotopic abundances, atomic weights and isotopic masses: see respective keyword.
[9] - C. Fry, M. Thoennessen:
Discovery of the thallium, lead, bismuth, and polonium isotopes.
In: Atomic Data and Nuclear Data Tables, (2013), DOI 10.1016/j.adt.2012.01.005.
Last update: 2022-12-12
Perma link: https://www.chemlin.org/chemical-elements/polonium-isotopes.php
© 1996 - 2023 ChemLin