The chemical element scandium, which is one of the rare earth metals, occurs in nature only in the form of its stable isotope Sc-45. All other Sc isotopes are unstable and decay with half-lives of a few days (Sc-46, Sc-47) or much less.
About 100 core isomers of scandium are known, of which Sc-44m with a Half-life of 58.6 hours is the most long-lived.
The standard atomic mass of scandium is given as 44.955908(5) u.
Isotope Nuclide | E | N | Atomic Mass [Nuclear Mass] {Mass Excess} | Spin I (h/2π) | Parent |
---|---|---|---|---|---|
1 | 2 | 3 | 4 | 5 | 6 |
Scandium-36 | 3621Sc | 15 | 36.01492(54) u [36.0034 u] {13.89789 MeV} | ||
Scandium-37 | 3721Sc | 16 | 37.00305(32) u [36.99153 u] {2.84106 MeV} | 7/2 | |
Scandium-38 | 3821Sc | 17 | 37.99544(21) u [37.98392 u] {-4.24761 MeV} | (2-) | |
Scandium-38m | 38m21Sc | 17 | 37.99544(21) u [37.98392 u] {-4.24761 MeV} | ||
Scandium-39 | 3921Sc | 18 | 38.984790(26) u [38.97327 u] {-14.16802 MeV} | (7/2-) | 43Cr |
Scandium-40 | 4021Sc | 19 | 39.977967(3) u [39.966447 u] {-20.52361 MeV} | 4- | 40Ti |
Scandium-41 | 4121Sc | 20 | 40.96925110(9) u [40.9577311 u] {-28.64242 MeV} | 7/2- | 41Ti 43Cr |
Scandium-42 | 4221Sc | 21 | 41.96551652(18) u [41.9539966 u] {-32.12115 MeV} | 0+ | 42Ti |
Scandium-42m | 42m21Sc | 21 | 41.96551652(18) u [41.9539966 u] {-32.12115 MeV} | 7+ | |
Scandium-43 | 4321Sc | 22 | 42.9611505(20) u [42.9496305 u] {-36.18808 MeV} | 7/2- | 43Ti |
Scandium-43m1 | 43m121Sc | 22 | 42.9611505(20) u [42.9496305 u] {-36.18808 MeV} | 3/2+ | |
Scandium-43m2 | 43m221Sc | 22 | 42.9611505(20) u [42.9496305 u] {-36.18808 MeV} | (19/2)- | |
Scandium-44 | 4421Sc | 23 | 43.9594029(19) u [43.9478829 u] {-37.81596 MeV} | 2+ | 44Ti |
Scandium-44m1 | 44m121Sc | 23 | 43.9594029(19) u [43.9478829 u] {-37.81596 MeV} | 1- | |
Scandium-44m2 | 44m221Sc | 23 | 43.9594029(19) u [43.9478829 u] {-37.81596 MeV} | 0- | |
Scandium-44m3 | 44m321Sc | 23 | 43.9594029(19) u [43.9478829 u] {-37.81596 MeV} | 6+ | |
Scandium-45 | 4521Sc | 24 | 44.955908(5) u [44.944388 u] {-41.07143 MeV} | 7/2- | 45Ca 45Ti |
Scandium-45m | 45m21Sc | 24 | 44.9559119(9) u [44.9443919 u] {-41.0678 MeV} | 3/2+ | |
Scandium-46 | 4621Sc | 25 | 45.9551719(9) u [45.9436519 u] {-41.75711 MeV} | 4+ | |
Scandium-46m1 | 46m121Sc | 25 | 45.9551719(9) u [45.9436519 u] {-41.75711 MeV} | 6+ | |
Scandium-46m2 | 46m221Sc | 25 | 45.9551719(9) u [45.9436519 u] {-41.75711 MeV} | 1- | |
Scandium-47 | 4721Sc | 26 | 46.9524075(22) u [46.9408875 u] {-44.33213 MeV} | 7/2- | 47Ca |
Scandium-47m | 47m21Sc | 26 | 46.9524075(22) u [46.9408875 u] {-44.33213 MeV} | (3/2)+ | |
Scandium-48 | 4821Sc | 27 | 47.952231(6) u [47.940711 u] {-44.49654 MeV} | 6+ | |
Scandium-49 | 4921Sc | 28 | 48.950024(4) u [48.938504 u] {-46.55234 MeV} | 7/2- | 49Ca |
Scandium-50 | 5021Sc | 29 | 49.952176(16) u [49.940656 u] {-44.54777 MeV} | 5+ | 50Ca |
Scandium-50m | 50m21Sc | 29 | 49.952176(16) u [49.940656 u] {-44.54777 MeV} | 2+ | |
Scandium-51 | 5121Sc | 30 | 50.953592(21) u [50.942072 u] {-43.22877 MeV} | (7/2)- | 51Ca |
Scandium-52 | 5221Sc | 31 | 51.95658(9) u [51.94506 u] {-40.44547 MeV} | 3(+) | 52Ca |
Scandium-53 | 5321Sc | 32 | 52.95823(10) u [52.94671 u] {-38.9085 MeV} | (7/2-) | 53Ca |
Scandium-54 | 5421Sc | 33 | 53.96362(29) u [53.9521 u] {-33.88775 MeV} | (3)+ | 54Ca |
Scandium-54m | 54m21Sc | 33 | 53.96362(29) u [53.9521 u] {-33.88775 MeV} | (4,5)+ | |
Scandium-55 | 5521Sc | 34 | 54.96762(49) u [54.9561 u] {-30.16178 MeV} | (7/2-) | 55Ca |
Scandium-56 | 5621Sc | 35 | 55.97332(63) u [55.9618 u] {-24.85226 MeV} | (1+) | 56Ca |
Scandium-57 | 5721Sc | 36 | 56.97779(75) u [56.96627 u] {-20.68848 MeV} | 7/2-~ | 57Ca |
Scandium-58 | 5821Sc | 37 | 57.98403(43) u [57.97251 u] {-14.87596 MeV} | (3+) | |
Scandium-59 | 5921Sc | 38 | 58.98922(97) u [58.9777 u] {-10.04151 MeV} | 7/2- | |
Scandium-60 | 6021Sc | 39 | 59.99571(97) u [59.98419 u] {-3.99611 MeV} | 3+ | |
Scandium-61 | 6121Sc | 40 | 61.00100(64) u [60.98948 u] {0.93149 MeV} | 7/2 |
Isotope | Radioactive Decay | Extern | |||
---|---|---|---|---|---|
Half-life | Decay Mode | Probability | Energy | ||
7 | 8 | 9 | 10 | 11 | 12 |
Sc-36 | p → 35Ca | AL | |||
Sc-37 | p → 36Ca | AL | |||
Sc-38 | 300 ns | p → 37Ca | ? | 0.900 MeV | AL |
Sc-38m | p → 37Ca | AL | |||
Sc-39 | 300 ns | p → 38Ca | 100 % | AL | |
Sc-40 | 182.3(7) ms | EC/β+ → 40Ca EC, p 39K EC, α → 36Ar | 99.54 % 0.44 % 0.017 % | 14.320(28) MeV 5.991 MeV 7.279 MeV | AL |
Sc-41 | 596.3(17) ms | EC/β+ → 41Ca | 6.49548(16) MeV | AL | |
Sc-42 | 680.79(28) ms | EC β+ → 42Ca | 100 % | 6.42609(22) MeV | AL |
Sc-42m | 61.7(4) s | EC β+ → 42Ca | 100 % | 7.042 MeV | AL |
Sc-43 | 3.891(12) h | EC/β+ → 43Ca | 100 % | 2.2207(19) MeV | AL |
Sc-43m1 | 438(7) μs | Iso → 43Sc | 100 % | AL | |
Sc-43m2 | 472(4) ns | AL | |||
Sc-44 | 3.97(4) h | EC β+ → 44Ca | 100 % | 3.6527(18) MeV | AL |
Sc-44m1 | 154.8(8) ns | AL | |||
Sc-44m2 | 51.0(3) μs | AL | |||
Sc-44m3 | 58.61(10) h | Iso → 44Sc EC β+ → 44Ca | 98.80(7) % 1.20(7) % | 0.271 MeV 3.924 MeV | AL |
Sc-45 | stable | AL | |||
Sc-45m | 318(7) ms | Iso → 45Sc | AL | ||
Sc-46 | 83.79(4) d | β- → 46Ti | 100 % | 2.3666(7) MeV | AL |
Sc-46m1 | 9.4(8) μs | AL | |||
Sc-46m2 | 18.75(4) s | Iso → 46Sc | 100 % | AL | |
Sc-47 | 3.3492(6) d | β- → 47Ti | 100 % | 0.6008(19) MeV | AL |
Sc-47m | 272(8) ns | AL | |||
Sc-48 | 43.67(9) h | β- → 48Ti | 100 % | 3.989(5) MeV | AL |
Sc-49 | 57.2(2) min | β- → 49Ti | 100 % | 2.0025(27) MeV | AL |
Sc-50 | 102.5(5) s | β- → 50Ti | 100 % | 6.884(15) MeV | AL |
Sc-50m | 0.35(4) s | Iso → 50Sc β- → 50Ti | 99.5(5) % < 1.0 % | 6.89 MeV | AL |
Sc-51 | 12.4(1) s | β- → 51Ti β-, n → 50Ti | 100 % ? | 6.504(20) MeV 0.132(20) MeV | AL |
Sc-52 | 8.2(2) s | β- → 52Ti | 100 % | 9.03(8) MeV | AL |
Sc-53 | 2.6(4) s | β- → 53Ti β-, n → 52Ti | > 99.9 % < 0.1 % | 7.92(14) MeV 2.49(9) MeV | AL |
Sc-54 | 526(15) ms | β- → 54Ti β-, n → 53Ti | 85(9) % 16(9) % | 11.73(28) MeV 4.87(29) MeV | AL |
Sc-54m | 2.77(2) μs | Iso → 54Sc | 100 % | AL | |
Sc-55 | 105(6) ms | β- → 55Ti β-, n → 54Ti | > 99.9 % < 0.1 % | 11.51(48) MeV 7.39(46) MeV | AL |
Sc-56 | 26(6) ms | β- → 56Ti β-, n → 55Ti | 100 % ? | 14.47(60) MeV 8.74(61) MeV | AL |
Sc-57 | 13(4) ms | β- → 57Ti | 100 % | 12.92(133) MeV | AL |
Sc-58 | 12(5) ms | β- → 58Ti | 100 % | 16.23(45) MeV | AL |
Sc-59 | 10 ms | β- → 59Ti β-, n → 58Ti | 100 % ? | 15.21(45) MeV 12.74(45) MeV | AL |
Sc-60 | 0.003 s | AL | |||
Sc-61 | 620 ns | β- → 61Ti β-, n → 60Ti β-, 2n → 59Ti | ? ? ? | 17.28(72) MeV | AL |
Notes (related to the columns):
1 - name of the nuclide, isotope.
2 - E: isotope symbol with mass number (superscript; number of nucleons) and Atomic number (subscript; number of protons).
3 - N: number of neutrons.
4 - relative atomic mass of the Scandium isotope (isotopic mass including electrons) and the mass of the atomic nucleus in square brackets (nuclear mass, nuclide mass without electrons), each related to 12C = 12.00000 [2]. In addition, the mass excess is given in MeV.
5 - nuclear spin I, unit: h/2π.
6 - source nuclides: Possible, assumed or actual source nuclides (mother nuclides, parent nuclides). If applicable, the corresponding decay modes can be found in the data for the respective starting nuclide.
7 - isotope notation in short form.
8 - decay: half-live of the Scandium isotope (a = years; ; d = days; h = hours; min = minutes; s = seconds).
9 - decay mode: type of decay into the respective daughter nuclides with n = neutron emission; p = proton emission; α = alpha decay; β- = beta minus decay with electron emission; EC = electron capture; β+ = positron emission; ε = β+ and/or EC; Iso = isomeric transition; CD = cluster decay; SF = spontaneous decay.
10 - decay probability in percent (%).
11 - decay energy; Particle energy related to decay type.
12 - other information and notes: AL = Adopted Levels (link to external data [1]).
Miscellaneous:
()- Numbers in brackets: uncertainty to represent the spread of the reported value.
~ - Theoretical values or systematic trends.
- unlisted-: Nuclides that have already been mentioned in the literature but for some reason can no longer be found in the current nuclide tables because their discovery e.g. has not confirmed.
Nuclide quantity 1) spin | Nuclear magnetic moment μ/μN | Gyromagnetic ratio {Quadrupole moment} | Resonant frequency v0 bei 1 T | Relative sensitivity H0 = const. v0 = const. 3) |
---|---|---|---|---|
45Sc 100 % 7/2- | +4,75400(8) | 6,5081 {- 0,220(2)} | 10,3591 | 0,30244 5,1094 |
1) Quantity Percentage of natural occurrence.
2) Gyromagnetic ratio: 107 rad T-1 s-1
Quadrupole moment: Q [barn] = [100 fm2]
3) Related to 1H = 1,000.
According to the Radiation Protection Ordinance (StrlSchV 2018, Germany), the following values (columns 1 to 7) apply to the handling of Scandium radionuclides:
Nuclide | Limit Value | HASS limit | SC | Daughter Nuclides | Half-life | |
---|---|---|---|---|---|---|
Sc-43 | 106 Bq | 10 Bq/g | 3.9 h | |||
Sc-44 | 105 Bq | 10 Bq/g | 0,03 TBq | 4.0 h | ||
Sc-44m+ | 107 Bq | 1 Bg/g | 2.4 d | |||
Sc-46 | 106 Bq | 0,1 Bq/g | 0,03 TBq | 1 Bq/cm2 | 83.8 d | |
Sc-47 | 106 Bq | 100 Bq/g | 0,7 TBq | 10 Bq cm-2 | 3.4 d | |
Sc-48 | 105 Bq | 1 Bq/g | 0,02 TBq | 1 Bq cm-2 | 43.7 h | |
Sc-49 | 105 Bq | 103 Bq/g | 57.2 min |
(HASS = High-Activity Sealed Radioactive Sources; SC = surface contamination)
Properties of the Scandium nucleides
[1] - NuDat: National Nuclear Data Center, Brookhaven National Laboratory, based on ENSDF and the Nuclear Wallet Cards.
[2] - G. Audi et. al.: The NUBASE evaluation of nuclear and decay properties. Nuclear Physics, (2003), DOI 10.1016/j.nuclphysa.2003.11.001.
[3] - Live Chart of Nuclides. Nuclear structure and decay data.
Scandium: NMR properties - 45Sc-NMR
[4] - N. J. Stone: Table of nuclear magnetic dipole and electric quadrupole moments. Atomic Data and Nuclear Data Tables, (2005), DOI 10.1016/j.adt.2005.04.001.
[5] - Pekka Pyykkö: Year-2008 nuclear quadrupole moments. Molecular Physics, (2008), DOI 10.1080/00268970802018367.
[6] - Pekka Pyykkö: Year-2017 nuclear quadrupole moments. Molecular Physics, (2018), DOI 10.1080/00268976.2018.1426131.
[7] - N. J. Stone: Table of recommended nuclear magnetic dipole moments. IAEA, (2019).
More sources:
[8] - Isotopic abundances, atomic weights and isotopic masses: see respective keyword.
Last update: 2022-12-12
Perma link: https://www.chemlin.org/chemical-elements/scandium-isotopes.php
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