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Sodium is a monoisotopic and mononuclide element: only one stable isotope of sodium 23Na occurs in nature. All other known isotopes are unstable.
The longest-lived artificial isotopes are 22Na, which undergoes β+ decay with a half-life of 2.602 years and 24Na, which also undergoes β+ decay with a half-life of 14.957 hours.
These nuclides are used as tracers in nuclear medicine. 22Na can be produced by irradiating magnesium or aluminum targets with protons from a cyclotron for several weeks. 24Na is formed from 23Na by neutron capture and can be produced in research reactors.
Isotope Nuclide | E | N | Atomic Mass [Nuclear Mass] {Mass Excess} | Spin I (h/2π) | Parent |
---|---|---|---|---|---|
1 | 2 | 3 | 4 | 5 | 6 |
Sodium-17 | 1711Na | 6 | 1.703727(6) u [1.6976927 u] {-14248.38652 MeV} | (1/2+) | |
Sodium-18 | 1811Na | 7 | 18.02688(10) u [18.0208457 u] {25.03856 MeV} | (1)- | |
Sodium-19 | 1911Na | 8 | 19.013880(11) u [19.0078457 u] {12.92914 MeV} | (5/2+) | |
Sodium-20 | 2011Na | 9 | 20.0073543(12) u [20.00132 u] {6.85049 MeV} | 2+ | 20Mg |
Sodium-21 | 2111Na | 10 | 20.99765446(5) u [20.9916201 u] {-2.18486 MeV} | 3/2+ | 21Mg 22Al 23Si |
Sodium-22 | 2211Na | 11 | 21.99443755(14) u [21.9884032 u] {-5.18139 MeV} | 3+ | 22Mg 23Al |
Sodium-22m1 | 22m111Na | 11 | 21.99443755(14) u [21.9884032 u] {-5.18139 MeV} | 1+ | |
Sodium-22m2 | 22m211Na | 11 | 21.99443755(14) u [21.9884032 u] {-5.18139 MeV} | 0+ | |
Sodium-23 | 2311Na | 12 | 22.98976928(2) u [22.9837349 u] {-9.52985 MeV} | 3/2+ | 23Mg 23Ne |
Sodium-24 | 2411Na | 13 | 23.990963012(18) u [23.9849287 u] {-8.4179 MeV} | 4+ | 24Ne |
Sodium-24m | 24m11Na | 13 | 23.990963012(18) u [23.9849287 u] {-8.4179 MeV} | 1+ | |
Sodium-25 | 2511Na | 14 | 24.9899540(13) u [24.9839197 u] {-9.35779 MeV} | 5/2+ | 25Ne |
Sodium-26 | 2611Na | 15 | 25.992635(4) u [25.9866007 u] {-6.86045 MeV} | 3+ | 26Ne |
Sodium-26m | 26m11Na | 15 | 25.992635(4) u [25.9866007 u] {-6.86045 MeV} | 1+ | |
Sodium-27 | 2711Na | 16 | 26.994076(4) u [26.9880417 u] {-5.51817 MeV} | 5/2+ | |
Sodium-28 | 2811Na | 17 | 27.998939(11) u [27.9929047 u] {-0.98832 MeV} | 1+ | 28Ne |
Sodium-29 | 2911Na | 18 | 29.002877(8) u [28.9968427 u] {2.67991 MeV} | 3/2+ | 29Ne |
Sodium-30 | 3011Na | 19 | 30.009098(5) u [30.0030637 u] {8.47473 MeV} | 2+ | 30Ne |
Sodium-31 | 3111Na | 20 | 31.013147(15) u [31.0071127 u] {12.24635 MeV} | 3/2+ | |
Sodium-32 | 3211Na | 21 | 32.02001(4) u [32.0139757 u] {18.63919 MeV} | (3-,4-) | 32Ne |
Sodium-33 | 3311Na | 22 | 33.02553(48) u [33.0194957 u] {23.78104 MeV} | (3/2+) | |
Sodium-34 | 3411Na | 23 | 34.03401(64) u [34.0279757 u] {31.68011 MeV} | 1+ | 34Ne |
Sodium-35 | 3511Na | 24 | 35.04104(72) u [35.0350057 u] {38.22851 MeV} | (3/2+) | |
Sodium-36 | 3611Na | 25 | 36.04971(73) u [36.0436757 u] {46.30457 MeV} | ||
Sodium-37 | 3711Na | 26 | 37.05747(74) u [37.0514357 u] {53.53296 MeV} | 3/2+ | |
Sodium-38 | 3811Na | 27 | |||
Sodium-39 | 3911Na | 28 | 39.07512(80) u [39.0690857 u] {69.97383 MeV} | 3/2+ |
Isotope | Radioactive Decay | Extern | |||
---|---|---|---|---|---|
Half-life | Decay Mode | Probability | Energy | ||
7 | 8 | 9 | 10 | 11 | 12 |
Na-17 | p → 16Ne | ? | AL | ||
Na-18 | 1.3(4) zs | p → 17Ne | ? 100 % | AL | |
Na-19 | 11.4 zs | p → 18Ne | ? 100 % | 0.832 MeV | AL |
Na-20 | 447.9(23) ms | β+ → 20Ne β+, α → 16O | 79.95(20) % 20.05(20) % | 13.8925(11) MeV 9.160 MeV | AL |
Na-21 | 22.4615(39) s | β+ → 21Ne | 100 % | 3.54692(6) MeV | AL |
Na-22 | 2.6018(22) a | EC β+ → 22Ne | 100 % | 2.84333(13) MeV | AL |
Na-22m1 | 243(2) ns | Iso → 22Na | AL | ||
Na-22m2 | 19.6(7) ps | Iso → 22Na | AL | ||
Na-23 | stable | AL | |||
Na-24 | 14.956(3) h | β- → 24Mg | 100 % | 5.515677(21) MeV | AL |
Na-24m | 20.18(10) ms | β- → 24Mg Iso → 24Na | ca. 0.05 % ca. 99.95 % | 5.987884(21) MeV 0.4722071(14) MeV | AL |
Na-25 | 59.1(6) s | β- → 25Mg | 100 % | 3.8350(12) MeV | AL |
Na-26 | 1.07128(25) s | β- → 26Mg | 100 % | 9.354(4) MeV | AL |
Na-26m | 9(2) μs | Iso → 26Na | 100 % | ||
Na-27 | 301(6) ms | β- → 27Mg β-, n → 26Mg | 98.7 % 0.13(4) % | 9.069(4) MeV 2.625(4) MeV | AL |
Na-28 | 30.5(4) ms | β- → 28Mg β-, n → 27Mg | 99.42 % 0.58(12) % | 14.032(10) MeV 5.527(10) MeV | AL |
Na-29 | 44.1(9) ms | β- → 29Mg β-, n → 28Mg | 78.5(30) % 21.5(30) % | 13.292(7) MeV 9.629(7) MeV | AL |
Na-30 | 48(2) ms | β- → 30Mg β-, n → 29Mg β-, 2n → 28Mg β-, α → 26Ne | 68.85 % 30(4) % 1.15 % 0.000055 % | 17.272 MeV 10.909 MeV 7.237 MeV 5.507 MeV | AL |
Na-31 | 17.0(4) ms | β- → 31Mg β-, n → 30Mg β-, 2n → 29Mg β-, 3n → 28Mg | 62.05 % 39(5) % 0.7(1) % > 0.05 % | 15.368(14) MeV 13.494 MeV 7.131 MeV 3.459 MeV | AL |
Na-32 | 13.2(4) ms | β- → 32Mg β-, n → 31Mg β-, 2n → 30Mg | 68 % 24(7) % 8.3 % | 20.019 MeV 14.211 MeV 11.833 MeV | AL |
Na-33 | 8.0(4) ms | β- → 33Mg β-, n → 32Mg β-, 2n → 31Mg | 40 % 47(6) % 13(3) % | 19.995 MeV 17.773 MeV 11.964 MeV | AL |
Na-34 | 5.5(10) ms | β- → 34Mg β-, n → 33Mg β-, 2n → 32Mg | ca. 35 % ca. 15 % ca. 50 % | 23.952 MeV 19.796 MeV 17.573 MeV | AL |
Na-35 | 1.8(5) ms | β- → 35Mg β-, n → 34Mg β-, xn | 23.430 MeV 22.702 MeV | AL | |
Na-36 | 180 ns | n ? | AL | ||
Na-37 | 60 ns | β- ? β-, n ? | AL | ||
Na-38 | noch unentdeckt | ||||
Na-39 | 1 ms | β- 39Mg β-, n 38Mg β-, 2n 37Mg | ? ? ? |
Notes (related to the columns):
1 - name of the nuclide, isotope.
2 - E: isotope symbol with mass number (superscript; number of nucleons) and Atomic number (subscript; number of protons).
3 - N: number of neutrons.
4 - relative atomic mass of the Sodium isotope (isotopic mass including electrons) and the mass of the atomic nucleus in square brackets (nuclear mass, nuclide mass without electrons), each related to 12C = 12.00000 [2]. In addition, the mass excess is given in MeV.
5 - nuclear spin I, unit: h/2π.
6 - source nuclides: Possible, assumed or actual source nuclides (mother nuclides, parent nuclides). If applicable, the corresponding decay modes can be found in the data for the respective starting nuclide.
7 - isotope notation in short form.
8 - decay: half-live of the Sodium isotope (a = years; ; d = days; h = hours; min = minutes; s = seconds).
9 - decay mode: type of decay into the respective daughter nuclides with n = neutron emission; p = proton emission; α = alpha decay; β- = beta minus decay with electron emission; EC = electron capture; β+ = positron emission; ε = β+ and/or EC; Iso = isomeric transition; CD = cluster decay; SF = spontaneous decay.
10 - decay probability in percent (%).
11 - decay energy; Particle energy related to decay type.
12 - other information and notes: AL = Adopted Levels (link to external data [1]).
Miscellaneous:
()- Numbers in brackets: uncertainty to represent the spread of the reported value.
~ - Theoretical values or systematic trends.
- unlisted-: Nuclides that have already been mentioned in the literature but for some reason can no longer be found in the current nuclide tables because their discovery e.g. has not confirmed.
Nuclide quantity 1) spin | Nuclear magnetic moment μ/μN | Gyromagnetic ratio {Quadrupole moment} | Resonant frequency v0 bei 1 T | Relative sensitivity H0 = const. v0 = const. 3) |
---|---|---|---|---|
23Na 100 % 3/2+ | +2,21750(3) | 7,0801 {+0,104(1)} | 11,2688 | 0,09270 1,3234 |
1) Quantity Percentage of natural occurrence.
2) Gyromagnetic ratio: 107 rad T-1 s-1
Quadrupole moment: Q [barn] = [100 fm2]
3) Related to 1H = 1,000.
According to the Radiation Protection Ordinance (StrlSchV 2018, Germany), the following values (columns 1 to 7) apply to the handling of Sodium radionuclides:
Nuclide | Limit Value | HASS limit | SC | Daughter Nuclides | Half-life | |
---|---|---|---|---|---|---|
Na-22 | 106 Bq | 10 Bq/g | 0,03 TBq | 1 Bq/cm2 | 2.6 a | |
Na-24 | 105 Bq | 1 Bq/g | 0,02 TBq | 1 Bq/cm2 | 15.0 h |
(HASS = High-Activity Sealed Radioactive Sources; SC = surface contamination)
Properties of the Sodium nucleides
[1] - NuDat: National Nuclear Data Center, Brookhaven National Laboratory, based on ENSDF and the Nuclear Wallet Cards.
[2] - G. Audi et. al.: The NUBASE evaluation of nuclear and decay properties. Nuclear Physics, (2003), DOI 10.1016/j.nuclphysa.2003.11.001.
[3] - Live Chart of Nuclides. Nuclear structure and decay data.
Sodium: NMR properties - 23Na-NMR
[4] - N. J. Stone: Table of nuclear magnetic dipole and electric quadrupole moments. Atomic Data and Nuclear Data Tables, (2005), DOI 10.1016/j.adt.2005.04.001.
[5] - Pekka Pyykkö: Year-2008 nuclear quadrupole moments. Molecular Physics, (2008), DOI 10.1080/00268970802018367.
[6] - Pekka Pyykkö: Year-2017 nuclear quadrupole moments. Molecular Physics, (2018), DOI 10.1080/00268976.2018.1426131.
[7] - N. J. Stone: Table of recommended nuclear magnetic dipole moments. IAEA, (2019).
More sources:
[8] - Isotopic abundances, atomic weights and isotopic masses: see respective keyword.
Last update: 2022-12-22
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